Comments by "SeanBZA" (@SeanBZA) on "In Defense of the CFL: A Retrospective" video.

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  6. The tubes shrinking from T12 to T8, and then to T5, was a result of increasing phosphor efficiency. The T12 phosphor was essentially the same phosphor since they were initially developed in the 1920's, and was very limited in operating temperature and allowed light emission. Thus you needed a certain area of phosphor to get a defined light output. Later improved phosphors allowed both higher light output, and higher operation temperature, and also the smaller diameter tubes allowed a reduction of volume of gas fill, and also a drop in the amount of mercury in them, so the mercury went from almost 100mg for a T12 lamp, to 5mg for T8, and down to under 2mg for a T5 tube. CFL units are at around 0.2mg of mercury per lamp typically, ironically making recovery of the mercury near impossible, as it is so little. The biggest killer of them in enclosed and any fixture is that most of the power dissipation is in the filament ends, where you have to heat up the emitter material, so generating all the heat right by the electronics, and also in a nice insulating plastic enclosure. green PCB at manufacture ends up at EOL as being charred black, along with pretty much the entire inside of the lamp. Drawback of LED units is that they are also full of large amounts of toxic metals, Gallium, not so bad but still a heavy metal, and Arsenic, part and parcel of the Gallium Arsenide used to make the light emitting diode chips used in there, plus of course the phosphors are pretty much the same ones used in the flourescent lamps, and those are also a witches brew of heavy metal oxides, enclosing the GaAs chip. Flourescent linear lamps are easy to recycle, mostly glass, a bit of nickel wire, some strontium and tungsten, and a little fill of aluminium and copper from the ends, plus the water soluble phosphor inside, because it is deposited using a water based slurry. Crush up the tubes and wash them, and the wash water has almost all the phosphor and mercury, because it tends to bind with the phosphor (which is why you see so many T5 lamps that are pink, because the tiny amount of mercury in them has been adsorbed onto the phosphor coat strongly), and then you simply use eddy current sorting to pull the metal parts out, and melt them down again, and the glass goes into a furnace to make new ones. CFL units harder to recycle, you have to separate the electronics and the tube, and then mostly just recover the copper and dump the rest, and the same for LED lamps, if recycled only the copper is stripped, all the rest is just more waste to be dumped or buried somewhere. There was a brief period where CFL units had replaceable glass, as the idea was to reuse the electronic unit ballast and have a simple east to replace light emitter, but the integrated CFL quickly killed that as they were cheaper to make. Still have a few of those units around, and they will outlast the LED units very likely, as I also have a good supply of the PL flourescent lamps they use.
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